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In Table 1, it can be seen that DH for O2 release is typically in<br>the range 250–325 kJ/mol O2, i.e. similar to that of CuO. Available<br>data is summarized in Fig. 9, where this is compared to the enthalpy of combustion at 900 C for methane (401 kJ/mol O2), carbon<br>(379 kJ/mol O2) and CO (562 kJ/mol O2). Most coals have an enthalpy of combustion per mol O2 in the same range as CH4. It is evident from Table 1 and Fig. 9 that, in most cases, the overall reaction<br>in the fuel reactor will be slightly exothermic when oxygen carriers<br>capable of releasing O2 are used. As explained above, this could be<br>favorable, since it simplifies closure of the heat balance for the fuel<br>reactor. It should be pointed out though, that endothermic reaction<br>in the fuel reactor using oxygen carriers with O2 release is a possibility, and would be the case for example, if Co3O4–CoO was used,<br>as seen in Fig. 9.
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