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IR photons have low energy not enough to induce electronic transitions as UV restricted to compounds with small energy differences in the possible vibrational and rotational states cause aThe alternating electrical field of the radiation interacts with fluctuations in the dipole moment of the molecule (electromagnetic radation consists of an oscillating electrical field and an oscillating magnetic field, perpendicular to each other) . frequency of the radiation should matches the vibrational frequency of the molecule absorbed change in the amplitude of molecular vibration
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