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The IR peaks at
1285.7 cm-1 (K2SO4,) is assigned to the group SOH HSO4 bending plane. The band appeared below700
cm-1 assigned for bending symmetrical and asymmetrical SO4 group. Therefore, we have assigned the
575 cm-1 frequency, 477.8 cm-1 (K2 SO4) 390 cm-1, 380 cm-1 (NaHSO4) 430 cm-1, 400 cm-1 (KHSO4)
for bending symmetrical SO4 group. The observed frequency band at 637.7 cm-1, 615.6 cm-1
(Na2SO4) 612.8 cm-1 (K2SO4) 610 cm-1 (NaHSO4) 605 cm-1 (KHSO4) is assigned as symmetrical
curvature of the SO4 groups. The observed peaks were assigned to the vibrational modes of the crystal.
Raman frequency sulfate (Na2SO4 and K2SO4) and hydrogen sulphate (NaHSO4 and KHSO4)
alongwith classification is given in the table.
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